CYCLO-GLYCOSYLATION OF (1-]4)-LINKED GLYCOHEXAOSES - SYNTHESIS OF CYCLO-LACTOHEXAOSE

被引：31

作者：

KUYAMA, H

NUKADA, T

NAKAHARA, Y

OGAWA, T

机构：

[1] INST PHYS & CHEM RES RIKEN,WAKO,SAITAMA 35101,JAPAN

[2] UNIV TOKYO,FAC AGR,BUNKYO KU,TOKYO 113,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 13期

关键词：

D O I：

10.1016/S0040-4039(00)60374-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclo-glycosylation of (2,3,6-tri-O-benzyl-beta-D-galactopyranosyl)-{(1-->4)-(2,3,6-tri-O-benzyl-beta-D-glucopyranosyl) -(1-->4)-(2,3,6-tri-O-benzyl-alpha-D-galactopyranosyl))2-(1-->4)-(2,3,6-tri-O-benzyl-alpha/beta-glucopyranosyl fluoride and subsequent deprotection of the product gave an excellent yield of cyclo-lactohexaose.

引用

页码：2171 / 2174

页数：4

共 18 条

[1] REDUCTIVE RING OPENINGS OF CARBOHYDRATE BENZYLIDENE ACETALS USING BORANE-TRIMETHYLAMINE AND ALUMINUM-CHLORIDE - REGIOSELECTIVITY AND SOLVENT DEPENDENCE
EK, M
GAREGG, PJ
HULTBERG, H
OSCARSON, S
[J]. JOURNAL OF CARBOHYDRATE CHEMISTRY, 1983, 2 (03) : 305 - 311
[2] PARA-ANISYL GROUP - A VERSATILE PROTECTING GROUP FOR PRIMARY ALCOHOLS
FUKUYAMA, T
LAIRD, AA
HOTCHKISS, LM
[J]. TETRAHEDRON LETTERS, 1985, 26 (51) : 6291 - 6292
[3] KOENERS HJ, 1981, RECL TRAV CHIM PAY B, V100, P65
[4] NEW GLYCOSIDATION REACTION .1. COMBINATIONAL USE OF CP2ZRCL2-AGCLO4 FOR ACTIVATION OF GLYCOSYL FLUORIDES AND APPLICATION TO HIGHLY BETA-SELECTIVE GLYCOSIDATION OF D-MYCINOSE
MATSUMOTO, T
MAETA, H
SUZUKI, K
TSUCHIHASHI, G
[J]. TETRAHEDRON LETTERS, 1988, 29 (29) : 3567 - 3570
[5] STEREOSELECTIVITY OF CYCLOGLYCOSYLATION IN MANNOOLIGOSE SERIES DEPENDS ON CARBOHYDRATE CHAIN-LENGTH - SYNTHESES OF MANNO ISOMERS OF BETA-CYCLODEXTRINS AND GAMMA-CYCLODEXTRINS
MORI, M
ITO, Y
UZAWA, J
OGAWA, T
[J]. TETRAHEDRON LETTERS, 1990, 31 (22) : 3191 - 3194
[6] AN APPROACH TO THE REGIOSELECTIVE INTRODUCTION OF FUNCTIONAL-GROUPS ON ALPHA-(1-]4) LINKED CYCLOMANNOHEXAOSE - ALKYLATION AT O-2
MORI, M
ITO, Y
OGAWA, T
[J]. TETRAHEDRON LETTERS, 1990, 31 (21) : 3029 - 3030
[7] A HIGHLY EFFICIENT AND STEREOSELECTIVE CYCLOGLYCOSYLATION - SYNTHESIS OF CYCLO(-]4)-[ALPHA-MAN-(1-]4)]5-ALPHA-MAN-(1-]), A MANNO ISOMER OF ALPHA-CYCLODEXTRIN
MORI, M
ITO, Y
OGAWA, T
[J]. TETRAHEDRON LETTERS, 1989, 30 (10) : 1273 - 1276
[8] MORI M, 1991, THESIS U TOKYO
[9] TOTAL SYNTHESIS OF CYCLO-L-RHAMNOHEXAOSE BY A STEREOSELECTIVE THERMAL GLYCOSYLATION
NISHIZAWA, M
IMAGAWA, H
KAN, Y
YAMADA, H
[J]. TETRAHEDRON LETTERS, 1991, 32 (40) : 5551 - 5554
[10] GLUCAN SYNTHESIS .5. TOTAL SYNTHESIS OF ALPHA-CYCLODEXTRIN
OGAWA, T
TAKAHASHI, Y
[J]. CARBOHYDRATE RESEARCH, 1985, 138 (01) : C5 - C9

← 1 2 →