SYNTHESIS AND SOME REACTIONS OF TRIS(CYCLOPENTADIENYL) - URANIUM(IV) HYDRIDES - CRYSTAL-STRUCTURE OF [U(C5H4BU(T))3H]

被引：39

作者：

BERTHET, JC ^{[1
]}

LEMARECHAL, JF ^{[1
]}

LANCE, M ^{[1
]}

NIERLICH, M ^{[1
]}

VIGNER, J ^{[1
]}

EPHRITIKHINE, M ^{[1
]}

机构：

[1] CEA CE SACLAY,DRECAM,SERV CHIM MOLEC,CNRS,URA 331,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 09期

关键词：

D O I：

10.1039/dt9920001573

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The uranium(IV) hydrides [U(C5H4R)3H] (R = SiMe3 1 or Bu(t( 2), which are thermally very stable, were isolated from the reactions of the corresponding chlorides with KBEt3H. The hydridic character of 1 and 2 was demonstrated by their reactions with chloroform and alcohols, and by treatment with NEt3HBPh4, which gives the cationic complexes [U(C5H4R)3][BPh4]. The crystal structure of 2 has been determined.

引用

页码：1573 / 1577

页数：5

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