CRYSTAL-STRUCTURE OF TRIS(N,N-DIETHYL-N'-BENZOYLTHIOUREATO) RHODIUM(III)

被引：25

作者：

BENSCH, W ^{[1
]}

SCHUSTER, M ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8046 GARCHING,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1992年 / 615卷 / 09期

关键词：

RHODIUM(III) COMPLEX; TRIS(N; N-DIETHYL-N'-BENZOYLTHIOUREATO)RHODIUM(III); PREPARATION; CRYSTAL STRUCTURE;

D O I：

10.1002/zaac.19926150918

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Rh(C12H15N2OS)3 crystallizes in the trigonal space group P-3. The cell parameters are a = 16.660(2), c = 8.479(1) angstrom and Z = 2. The structure was solved with Patterson and direct methods and refined to a final R-value of 7.05%. Rh(III) is octahedrally coordinated to three N,N-Diethyl-N'-benzoylthiourea molecules, which are bidentately coordinated through their oxygen and sulfur atoms. The Rh-S and Rh-O bond lengths are 2.284 angstrom and 2.033 angstrom, respectively.

引用

页码：93 / 96

页数：4

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