ELECTROCHEMICAL PROPERTIES OF POLY(ISOTHIANAPHTHENE)

被引：23

作者：

ONODA, M ^{[1
]}

MORITA, S ^{[1
]}

NAKAYAMA, H ^{[1
]}

YOSHINO, K ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT ELECTR ENGN,SUITA,OSAKA 565,JAPAN

来源：

JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 1993年 / 32卷 / 08期

关键词：

CONDUCTING POLYMER; POLY(ISOTHIANAPHTHENE); TRANSPARENCY; ELECTROCHEMICAL DOPING; ABSORPTION SPECTRUM; BAND GAP; ELECTRON SPIN RESONANCE; POLARON; BIPOLARON; ELECTRONIC STATE;

D O I：

10.1143/JJAP.32.3534

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Electrochemical, optical, and magnetic properties of poly(isothianaphthene) as a function of doping potential and electronic states, are discussed in detail. The band gap of poly(isothianaphthene) has been evaluated to be 1.0 eV and the evolution of localized states is evidenced by the spectral change with electrochemical doping. The magnetic susceptibility evaluated from electron spin resonance measurement has exhibited the highest value at a doping potential of 3.5 V vs Li/Li+. These results are interpreted in terms of the polaron and/or bipolaron models. The electronic band structure of poly(isothianaphthene) has been determined. The top of the valence band of poly(isothianaphthene) is located at an energy state higher than that of polythiophene by about 0.5 eV. On the other hand, the bottom of the conduction band of poly(isothianaphthene) is located at an energy state lower than that of polythiophene by about 0.6 eV, suggesting successful electrochemical n-type doping.

引用

页码：3534 / 3539

页数：6

共 17 条

[1] BIPOLARONS IN POLYPYRROLE CHAINS [J].

BREDAS, JL ;

THEMANS, B ;

ANDRE, JM .

PHYSICAL REVIEW B, 1983, 27 (12) :7827-7830

[2] SIMPLE SYNTHETIC ROUTE TO BENZO[C]THIOPHENE AND NAPHTHO[C]THIOPHENES [J].

CAVA, MP ;

POLLACK, NM ;

MAMER, OA ;

MITCHELL, MJ .

JOURNAL OF ORGANIC CHEMISTRY, 1971, 36 (25) :3932-&

[3]

CHEN JCW, 1981, MACROMOLECULES, V14, P479

[4] POLYACETYLENE, (CH) - PHOTOELECTROCHEMICAL SOLAR-CELL [J].

CHEN, SN ;

HEEGER, AJ ;

KISS, Z ;

MACDIARMID, AG ;

GAU, SC ;

PEEBLES, DL .

APPLIED PHYSICS LETTERS, 1980, 36 (01) :96-98

[5] STABILITY AND STABILIZATION OF POLYACETYLENE, POLYPHENYLACETYLENE, AND ACETYLENE/PHENYLACETYLENE COPOLYMERS [J].

DEITS, W ;

CUKOR, P ;

RUBNER, M ;

JOPSON, H .

SYNTHETIC METALS, 1982, 4 (03) :199-210

[6] ELECTROCHEMICAL AND MAGNETIC-PROPERTIES OF POLYAZULENE [J].

HAYASHI, S ;

NAKAJIMA, S ;

KANETO, K ;

YOSHINO, K .

JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1986, 55 (11) :3995-4002

[7] ELECTROCHEMICAL PREPARATION OF A METALLIC POLYTHIOPHENE FILM [J].

KANETO, K ;

KOHNO, Y ;

YOSHINO, K ;

INUISHI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (07) :382-383

[8] ORGANIC SULFUR MECHANISMS .8. CHLORINATION OF HETEROCYCLIC AND ACYCLIC SULFONHYDRAZONES [J].

KING, JF ;

HAWSON, A ;

HUSTON, BL ;

DANKS, LJ ;

KOMERY, J .

CANADIAN JOURNAL OF CHEMISTRY, 1971, 49 (06) :943-&

[9] THE ELECTRONIC AND ELECTROCHEMICAL PROPERTIES OF POLY(ISOTHIANAPHTHENE) [J].

KOBAYASHI, M ;

COLANERI, N ;

BOYSEL, M ;

WUDL, F ;

HEEGER, AJ .

JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (12) :5717-5723

[10]

KURTI J, 1990, J CHEM PHYS, V92, P3247, DOI 10.1063/1.457883

← 1 2 →