DIAZENES .2. PREPARATION OF PHENYLDIAZENE

被引：54

作者：

HUANG, PKC

KOSOWER, EM

机构：

[1] Department of Chemistry, State University of New York at Stony Brook, Stony Brook

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1968年 / 90卷 / 09期

关键词：

D O I：

10.1021/ja01011a028

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The preparation of phenyldiazene (phenyldiimide), C6H6N=NH (3), by decarboxylation of phenyldiazenecarboxylate anion, C6H6N=NCOO- (2), is described. All work was carried out in oxygen-free systems because of the sensitivity of 3 to oxygen. The proof of structure of 3 depends upon (1) method of generation, (2) ultraviolet-visible spectra (very similar to that of C6H5N=NCH3), (3) reduction to phenylhydrazine, and (4) volatility. Phenyldiazene is the first monosubstituted diazene to be directly observed and characterized. © 1968, American Chemical Society. All rights reserved.

引用

页码：2362 / &

共 23 条

[1] INFRARED SPECTRUM OF DIIMIDE [J].