STUDIES OF AUSTRALIAN SOFT CORALS .41. STRUCTURE DETERMINATION OF A NEW SESQUITERPENE FROM XENIA-NOVAE-BRITANNIAE AND AN INVESTIGATION OF A XENIA SPECIES

被引：9

作者：

BOWDEN, BF

COLL, JC

ENGELHARDT, LM

HEATON, A

WHITE, AH

机构：

[1] JAMES COOK UNIV N QUEENSLAND, DEPT CHEM & BIOCHEM, TOWNSVILLE, QLD 4811, AUSTRALIA

[2] UNIV WESTERN AUSTRALIA, DEPT PHYS & INORGAN CHEM, NEDLANDS, WA 6009, AUSTRALIA

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1987年 / 40卷 / 08期

关键词：

D O I：

10.1071/CH9871483

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel sesquiterpene (1 Z,2R*,4R*,7S*,11S*)-3,3,7,11-tetramethyltricyclo[6.3.0.02,4]undec-1(8)-en-4-ol (3) was isolated from the soft coral Xenia novae-britanniae. Its structure was tentatively deduced by n.m.r. spectroscopy, and the structure with relative stereochemistry was confirmed by single-crystal X-ray crystallography. Investigation of a Xenia species afforded the known metabolite waixenicin-A previously isolated from Anthelia edmondsoni.

引用

页码：1483 / 1489

页数：7

共 17 条

[1]

BAYER F M, 1981, Proceedings of the Biological Society of Washington, V94, P902

[2]

BRAEKMAN JC, 1979, B SOC CHIM BELG, V88, P71

[3]

CLERC JT, 1973, 13C KERNRESONANZSPEC

[4] THE APPLICATION OF VACUUM LIQUID-CHROMATOGRAPHY TO THE SEPARATION OF TERPENE MIXTURES [J].