PSEUDOPOTENTIAL METHOD FOR INELASTIC PROCESSES IN ATOMS AND MOLECULES .2. PHOTOIONIZATION OF N2

被引：40

作者：

SCHNEIDER, B

BERRY, RS

机构：

[1] Department of Chemistry, James Franck Institute, University of Chicago, Chicago

[2] Department of Chemistry, University of Southern California, Los Angeles, CA

来源：

PHYSICAL REVIEW | 1969年 / 182卷 / 01期

关键词：

D O I：

10.1103/PhysRev.182.141

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The pseudopotential method developed in Paper I is applied to the photoionization of N2. From the known quantum defects of two Rydberg series of N2, we obtain the phase shifts of the photoionized electron. These phase shifts are used to construct a simple model potential approximation to the true pseudopotential. The model wave functions are then orthogonalized to the known Hartree-Fock wave functions of the N2+ core. Using these wave functions we calculate the total and differential cross section for photoionization of electrons from N2 as a function of the energy of the outgoing electron. The results of the calculation are discussed and compared with some of the more recent experimental measurements of the aforementioned quantities. © 1969 The American Physical Society.

引用

页码：141 / +

页数：1

共 19 条

[1] SPEKTREN UND WINKELVERTEILUNGEN DER PHOTOELEKTRONEN VON ATOMEN UND MOLEKULEN [J].