MEAN AMPLITUDES OF VIBRATION FOR SOME PYRAMIDAL XY3 MOLECULES

被引：11

作者：

CYVIN, SJ

CYVIN, BN

MULLER, A

机构：

[1] Institute of Theoretical Chemistry, Technical University of Norway

[2] Institute of Inorganic Chemistry, University of Göttingen

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1969年 / 4卷 / 5-6期

关键词：

D O I：

10.1016/0022-2860(69)85001-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Mean amplitudes of vibration calculated from spectroscopic data are reported for sixteen pyramidal XY3 molecules. For all molecules the L-matrix approximation method was used. In addition more accurate calculations were performed for some of the molecules, viz. NF3, PF3, PCl3 and AsF3, for which experimental Coriolis constants or centrifugal distortion constants are available. The accurate calculations confirmed the validity of the L-matrix approximation method. © 1969.

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页码：341 / &

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