COMPENSATION EFFECT AND ISOKINETIC TEMPERATURE IN THERMAL-DISSOCIATION REACTIONS OF THE TYPE-ASOLID REVERSIBLE BSOLID + CGAS

被引:50
作者
PYSIAK, J [1 ]
SABALSKI, B [1 ]
机构
[1] UNIV WARSAW,INST MATH,PL-02089 WARSAW,POLAND
来源
JOURNAL OF THERMAL ANALYSIS | 1979年 / 17卷 / 02期
关键词
D O I
10.1007/BF01914020
中图分类号
O414.1 [热力学];
学科分类号
摘要
It is shown that the Zawadzki - Bretsznajder rule, compensation effect, and isokinetic temperature are simple consequences of interpretation of the Arrhenius equation as a projection correlation. It is established that such an interpretation of the Arrhenius equation allows the discrimination of the deviation factors which impart a definite (although not always simple and recognized) physical sense, to the known empirical correlation. A possibility of deriving new correlation relationships by this method of reasoning is presented. © 1979 Wiley Heyden Ltd., Chichester and Akadémiai Kiadó, Budapest.
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页码:287 / 303
页数:17
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