NOVEL AND ENANTIOSELECTIVE TOTAL SYNTHESIS OF DRIMANE TYPE SESQUITERPENES

被引：22

作者：

SHISHIDO, K

OMODANI, T

SHIBUYA, M

机构：

[1] Faculty of Pharmaceutical Sciences, University of Tokushima, Tokushima 770

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 09期

关键词：

D O I：

10.1039/p19910002285

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two drimane type sesquiterpenoids, (+)-drimane-8,11-diol 1 and (+)-drim-9(11)-en-8-ol 2, have been synthesized in an optically pure form starting from geraniol.

引用

页码：2285 / 2287

页数：3

共 15 条

[1]

FUJIMOTO Y, 1976, TETRAHEDRON LETT, P3325

[2] TOBACCO CHEMISTRY .25. 2 NEW DRIMANE SESQUITERPENE ALCOHOLS FROM GREEK NICOTIANA-TABACUM-L [J].

HLUBUCEK, JR ;

AASEN, AJ ;

ALMQVIST, SO ;

ENZELL, CR .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1974, B 28 (03) :289-294

[3] STEREOSELECTIVE TOTAL SYNTHESIS OF TESTOSTERONE AND ANDROSTERONE VIA A/B-RING CONSTRUCTION OF THE STEROIDAL RING-SYSTEM BY INTRAMOLECULAR DIELS-ALDER REACTION [J].

IHARA, M ;

SUDOW, I ;

FUKUMOTO, K ;

KAMETANI, T .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (01) :117-123

[4] SEQUENTIAL RADICAL CYCLIZATION APPROACH TO PROPELLANE TRIQUINANES - TOTAL SYNTHESIS OF (+/-)-MODHEPHENE [J].

JASPERSE, CP ;

CURRAN, DP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (14) :5601-5609

[5] ALLYLIC STRAIN IN 6-MEMBERED RINGS [J].

JOHNSON, F .

CHEMICAL REVIEWS, 1968, 68 (04) :375-+

[6] THE 1ST PRACTICAL METHOD FOR ASYMMETRIC EPOXIDATION [J].

KATSUKI, T ;

SHARPLESS, KB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (18) :5974-5976

[7] ABSOLUTE-CONFIGURATION OF DRIM-9(11)-EN-8-OL FROM ASPERGILLUS-ORYZAE [J].

LEITE, MAF ;

SARRAGIOTTO, MH ;

IMAMURA, PM ;

MARSAIOLI, AJ .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (26) :5409-5410

[8] SYNTHESIS OF 7(8)-DESOXYASPERDIOL - A PRECURSOR OF THE CEMBRANOID ASPERDIOL [J].

MARSHALL, JA ;

CLEARY, DG .

JOURNAL OF ORGANIC CHEMISTRY, 1986, 51 (06) :858-863

[9] *ZUR KENNTNIS DER TRITERPENE .105. UBER DAS AMBREIN, EINEN BESTANDTEIL DES GRAUEN AMBRA [J].

RUZICKA, L ;

LARDON, F .

HELVETICA CHIMICA ACTA, 1946, 29 (04) :912-921

[10] ALLYLIC OXIDATION WITH 3,5-DIMETHYLPYRAZOLE - CHROMIUM TRIOXIDE COMPLEX - STEROIDAL DELTA-5-7-KETONES [J].

SALMOND, WG ;

BARTA, MA ;

HAVENS, JL .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (10) :2057-2059

← 1 2 →