STEREOSELECTIVE SYNTHESIS OF C-GLYCOSYL ALPHA-AMINO-ACIDS

被引：60

作者：

COLOMBO, L ^{[1
]}

CASIRAGHI, G ^{[1
]}

PITTALIS, A ^{[1
]}

RASSU, G ^{[1
]}

机构：

[1] CNR, IST APPLICAZ TECN CHIM AVANZATE PROBLEMI AGROBIOL, I-07100 SASSARI, ITALY

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 12期

关键词：

D O I：

10.1021/jo00012a021

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

beta-D-C-Allosyl-(R)-alanine 12 and beta-D-C-altrosyl-(R)-alanine lactone 15 were synthesized from the common intermediate 7 in just a few steps. The beta-C-glycosyloxazolone 7 was obtained in two steps from the protected D-glucal 4 by a sequential coupling with N-benzoylalanine followed by a Claisen rearrangement.

引用

页码：3897 / 3900

页数：4

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