STEREOCHEMISTRY OF OXIDATION AT SULFUR OXIDATION OF 2-THIABICYCLO[2.2.1]HEPTANE

被引：47

作者：

JOHNSON, CR

DIEFENBA.H

KEISER, JE

SHARP, JC

机构：

[1] Department of Chemistry, Wayne State University, Detroit

来源：

TETRAHEDRON | 1969年 / 25卷 / 23期

关键词：

D O I：

10.1016/S0040-4020(01)83071-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of 2-thiabicyclo[2.2.1]heptane by a variety of oxidizing agents provided both endo and exo sulfoxides. The ratio of these sulfoxide isomers is a function of the relative stability of the sulfoxides and/or the mechanism of the oxidation reaction. It has been demonstrated that the exo oxide of 2-thiabicyclo[2.2.1]heptane is thermodynamically more stable than the corresponding endo oxide, a result not to be predicted from referenced researches in the field. © 1969.

引用

页码：5649 / &

共 7 条

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[7] CHEMISTRY SULFOXI 21

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