ONE-DIMENSIONAL DONOR-ACCEPTOR POLYMER - PHOSPHORUS PORPHYRINS LINKED WITH MOLECULAR WIRE

被引：22

作者：

SEGAWA, H

NAKAYAMA, N

WU, F

SHIMIDZU, T

机构：

[1] Division of Molecular Engineering, Graduate School of Engineering, Kyoto University, Kyoto

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 2-3期

关键词：

D O I：

10.1016/0379-6779(93)90183-W

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

One-dimensional phosphorus(V)porphyrin polymers linked with the various length of oligothienyl molecular wire toward the axial direction of the porphyrin ring were synthesized by the electrochemical polymerization of symmetrical phosphorus(V)porphyrin triads with two oligothienyl axial groups. In the polymers, the phosphorus(V)porphyrin unit tending to be an electron acceptor acted as a photoinduced hole generator, and the oligothienyl moiety tending to be an electron donor was able to transfer the positive hole just as molecular electric wire. The conductivity of these donor-acceptor polymers was strongly enhanced by the photoirradiation, indicating that the photoinduced carrier formation and transfer occurs efficiently along the polymeric chain.

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页码：966 / 971

页数：6

相关论文

共 14 条

[1] UNUSUAL METALLOPORPHYRINS - PHOSPHORUS COMPLEXES OF TETRAPHENYLPORPHINE [J].

CARRANO, CJ ;

TSUTSUI, M .

JOURNAL OF COORDINATION CHEMISTRY, 1977, 7 (02) :79-83

[2] ELECTROACTIVE POLYMERS AND MACROMOLECULAR ELECTRONICS [J].

CHIDSEY, CED ;

MURRAY, RW .

SCIENCE, 1986, 231 (4733) :25-31

[3] A MOLECULAR SHIFT REGISTER BASED ON ELECTRON-TRANSFER [J].

HOPFIELD, JJ ;

ONUCHIC, JN ;

BERATAN, DN .

SCIENCE, 1988, 241 (4867) :817-820

[4] MECHANISM OF ELECTROCHEMICAL REDUCTION OF THE (5,10,15,20-TETRAPHENYLPORPHINATO)DIHYDROXOPHOSPHORUS(V) CATION [J].

MARRESE, CA ;

CARRANO, CJ .

INORGANIC CHEMISTRY, 1984, 23 (24) :3961-3968

[5] REDOX CHEMISTRY OF DICHLOROPHOSPHORUS(V)TETRAPHENYLPORPHINE - ISOLATION AND CHARACTERIZATION OF A STABLE PORPHYRIN ANION RADICAL AND POSSIBLE EVIDENCE FOR INTERNAL ELECTRON-TRANSFER [J].

MARRESE, CA ;

CARRANO, CJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (21) :1279-1280

[6] SYNTHESIS, CHARACTERIZATION, AND ELECTROCHEMISTRY OF (5,10,15,20-TETRAPHENYLPORPHINATO)DICHLOROPHOSPHORUS(V) CHLORIDE [J].

MARRESE, CA ;

CARRANO, CJ .

INORGANIC CHEMISTRY, 1983, 22 (13) :1858-1862

[7] PHOTODRIVEN CHARGE SEPARATION IN A CAROTENOPORPHYRIN QUINONE TRIAD [J].

MOORE, TA ;

GUST, D ;

MATHIS, P ;

MIALOCQ, JC ;

CHACHATY, C ;

BENSASSON, RV ;

LAND, EJ ;

DOIZI, D ;

LIDDELL, PA ;

LEHMAN, WR ;

NEMETH, GA ;

MOORE, AL .

NATURE, 1984, 307 (5952) :630-632

[8] PORPHYRINS .34. PHOSPHORUS COMPLEXES OF OCTAETHYLPORPHYRIN [J].

SAYER, P ;

GOUTERMAN, M ;

CONNELL, CR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (04) :1082-1087

[9] ELECTROCHEMICAL SYNTHESIS OF ONE-DIMENSIONAL DONOR-ACCEPTOR POLYMERS CONTAINING OLIGOTHIOPHENES AND PHOSPHORUS PORPHYRINS [J].

SEGAWA, H ;

NAKAYAMA, N ;

SHIMIDZU, T .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (10) :784-786

[10] SYNTHESIS OF AXIAL DIALKOXY PHOSPHORUS(V)PORPHYRIN DERIVATIVES - NOVEL HYPERVALENT PHOSPHORUS-COMPOUNDS [J].

SEGAWA, H ;

KUNIMOTO, K ;

NAKAMOTO, A ;

SHIMIDZU, T .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (08) :939-940