WEAK POLAR HOST-GUEST INTERACTIONS STABILIZING A MOLECULAR CLUSTER IN A CYCLODEXTRIN CAVITY - C-H-O AND C-H-X CONTACTS IN BETA-CYCLODEXTRIN-BUT-2-YNE-L,4-DIOL HEPTAHYDRATE

被引：60

作者：

STEINER, T

SAENGER, W

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 20期

关键词：

D O I：

10.1039/c39950002087

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the crystalline title complex, the guest molecules are ordered and the inclusion geometry is stabilized by a system of host-guest O-H...O, C-H...O and C-H...pi contacts; this is an example of weak but crucial polar interactions between the surface of a cyclodextrin cavity and a cluster of polar guest molecules.

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页码：2087 / 2088

页数：2

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