FACILE FORMATION AND REACTIONS OF MIXED TRIMETHYLSTANNYLMETHYLCUPRATES

被引:36
作者
OEHLSCHLAGER, AC
HUTZINGER, MW
AKSELA, R
SHARMA, S
SINGH, SM
机构
[1] Department of Chemistry, Simon Fraser University Burnaby
关键词
D O I
10.1016/S0040-4039(00)94360-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Solutions comprised of equimolar concentrations of methyllithium, trimethylstannyllithium and cuprous cyanide as well as reaction of Me2Cu(CN)Li2 with one equivalent of hexamethylditin give Me3Sn(Me)Cu(CN)Li2 which selectively delivers the R3Sn moviety to a variety of substrates. © 1990.
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页码:165 / 168
页数:4
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