CONVENIENT AND SHORT ROUTE TO A KEY INTERMEDIATE IN THE SYNTHESIS OF FORSKOLIN

被引：3

作者：

BACIGALUPPO, JA ^{[1
]}

COLOMBO, MI ^{[1
]}

ZINCZUK, J ^{[1
]}

HUBER, SN ^{[1
]}

MISCHNE, MP ^{[1
]}

RUVEDA, EA ^{[1
]}

机构：

[1] UNIV NACL ROSARIO,CONSEJO NACL INVEST CIENT & TECN,FAC CIENCIAS BIOQUIM & FARMACEUT,RA-2000 ROSARIO,ARGENTINA

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 12-13期

关键词：

D O I：

10.1080/00397919108021283

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intermediate 2, previously used in several synthetic sequences toward forskolin (1), has been synthesized from enone 3. The key step in the sequence is the 1,3-oxidative rearrangement of the tertiary alcohol 5, which allowed the easy introduction of the keto group at C-6 of 2.

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页码：1361 / 1367

页数：7

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