CRYSTAL-STRUCTURES OF 2 FLUORODIAZADIPHOSPHETIDINES

被引:3
作者
JONES, PG
SCHMUTZLER, R
机构
[1] Institut für Anorganische und Analytische Chemie der Technischen Universität, Federal, Hagenring 30
来源
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1991年 / 56卷 / 1-4期
关键词
FLUORODIAZADIPHOSPHETIDINES; X-RAY STRUCTURE;
D O I
10.1080/10426509108038080
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The crystal structures of the dilluorodiazadiphosphctidines [RF2PNR']2 (le: R = R' = Me and 1a: R = Ph. R' = Me) have been determined at -95°C. 1e: P2,//n. Z = 2. R = 0. 031 and la: Pbca. Z = 4. R = 0. 032. Both molecules are associated with crystallographic inversion centres, and the P2N2 rings are therefore exactly planar. The bond lengths follow the usual pattern for trigonal bipyramidal phosphorus. © 1991, Taylor & Francis Group, LLC. All rights reserved.
引用
收藏
页码:173 / 177
页数:5
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