POLY(O-ETHOXYANILINE) - CONTROL OF STRUCTURE AND CHARGE-TRANSPORT THROUGH DERIVATIZATION

被引：18

作者：

POUGET, JP

ZHAO, SL

WANG, ZH

OBLAKOWSKI, Z

EPSTEIN, AJ

MANOHAR, SK

WIESINGER, JM

MACDIARMID, AG

HSU, CH

机构：

[1] OHIO STATE UNIV,DEPT PHYS,COLUMBUS,OH 43210

[2] UNIV PENN,DEPT PHYS,PHILADELPHIA,PA 19104

[3] DUPONT CO INC,EXPTL STN F302,DIV FIBERS,WILMINGTON,DE 19880

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0379-6779(93)90955-V

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

It is shown that a large ring substituent such as -OC2H5 causes the polyaniline HCl salt to form a different crystal structure. Though there is substantial crystallinity, the bulky side groups make it more difficult to achieve three-dimensional metallic delocalization and, for the samples studied, the conduction electrons behave as if localized to single chains.

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收藏

页码：341 / 346

页数：6

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