THE FIRST MONONUCLEAR NITROSYL(OXO)MOLYBDENUM COMPLEX - SIDE-ON BONDED AND MU(3)-BRIDGING NO LIGANDS IN [(MOL(NO)(O)(OH))(2)]NAPF6-CENTER-DOT-H2O

被引：21

作者：

BOHMER, J

HASELHORST, G

WIEGHARDT, K

NUBER, B

机构：

[1] RUHR UNIV BOCHUM, LEHRSTUHL ANORGAN CHEM 1, D-44780 BOCHUM, GERMANY

[2] UNIV HEIDELBERG, INST ANORGAN CHEM, W-6900 HEIDELBERG, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1994年 / 33卷 / 14期

关键词：

D O I：

10.1002/anie.199414731

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Linked through sodium ions to form a tetranuclear complex, the neutral unit [MoL(NO)(O)(OH)] of the title compound displays two types of bonding between the Na+ ions and NO (shown on the right) in the crystalline state. The bonding in this and similar monomeric nitrosyloxo complexes can be described by a synergistic bonding model. L = 1,4,7‐triiso‐propyl‐1,4,7‐triazacyclononane. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1473 / 1476

页数：4

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