EXPONENTIATING TRAJECTORIES AND STATISTICAL BEHAVIOR - 3 DIMENSIONAL K+NACL AND H+LCL

被引:34
作者
DUFF, JW [1 ]
BRUMER, P [1 ]
机构
[1] UNIV TORONTO,DEPT CHEM,TORONTO M5S 1A1,ONTARIO,CANADA
关键词
D O I
10.1063/1.438627
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The dynamic origin of statistical behavior in three dimensional bimolecular collisions is explored using the exponentiating trajectories technique; NaCl + K and H + ICl are explicitly considered. The reported results provide further evidence that statistical product distributions are associated with trajectories characterized by extensive exponential divergence of initially adjacent phase space neighbors. A technique for testing the statisticality of product distributions is introduced and its role as a numerical method for general trajectory studies of long-lived dynamics is discussed. © 1979 American Institute of Physics.
引用
收藏
页码:2693 / 2702
页数:10
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