ESR AND OPTICAL STUDIES ON THE CATION-RADICAL OF PYRIDINE IN A GAMMA-IRRADIATED RIGID MATRIX AT LOW-TEMPERATURES

被引：104

作者：

SHIDA, T

KATO, T

机构：

[1] Department of Chemistry, Faculty of Science, Kyoto University, Kyoto

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80079-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Evidence for the cation-radical of pyridine is obtained by ESR and optical studies of γ-irradiated frozen solutions of pyridine in trichlorofluoromethane at 77 and 4 K. The cation-radical is a σ-type radical, the positive charge residing mostly in the nitrogen lone pair orbital. Consistent spectral data are obtained also for 2-deutero-, 4-deutero-, 2,6-dideutero-, and perdeutero-pyridines. © 1979.

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页码：106 / 110

页数：5

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