A CHIRAL PROBE USEFUL FOR OPTICAL RESOLUTION AND X-RAY CRYSTALLOGRAPHIC DETERMINATION OF THE ABSOLUTE STEREOCHEMISTRY OF CARBOXYLIC-ACIDS

被引：31

作者：

HARADA, N

SOUTOME, T

MURAI, S

UDA, H

机构：

[1] Institute for Chemical Reaction Science, Tohoku University, Sendai, 980, 2-1-1 Katahira, Aoba

来源：

TETRAHEDRON-ASYMMETRY | 1993年 / 4卷 / 08期

关键词：

D O I：

10.1016/S0957-4166(00)80409-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

(1S,2R,4R)-(-)-2,10-Camphorsultam is a very useful chiral probe for optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids. The absolute configurations of 2,6-dimethylspiro[3.3]heptane-2,6-dicarboxylic acid and [2.2]paracyclophane-4-carboxylic acid are determined.

引用

收藏

页码：1755 / 1758

页数：4

相关论文

共 9 条

[1] DETERMINATION OF THE ABSOLUTE CONFIGURATION OF OPTICALLY ACTIVE COMPOUNDS BY MEANS OF X-RAYS [J].

BIJVOET, JM ;

PEERDEMAN, AF ;

VANBOMMEL, AJ .

NATURE, 1951, 168 (4268) :271-272

[2]

HARADA N, 1993, MAR ANN M CHEM SOC J

[3]

HARADA N, 1983, CIRCULAR DICHROIC SP

[4] DISPERSION CORRECTIONS + CRYSTAL STRUCTURE REFINEMENTS [J].

IBERS, JA ;

HAMILTON, WC .

ACTA CRYSTALLOGRAPHICA, 1964, 17 (06) :781-&

[5] STATISTICAL EVALUATION OF ABSORPTION [J].

KATAYAMA, C ;

SAKABE, N ;

SAKABE, K .

ACTA CRYSTALLOGRAPHICA SECTION A-CRYSTAL PHYSICS DIFFRACTION THEORETICAL AND GENERAL CRYSTALLOGRAPHY, 1972, 28 (03) :293-&

[6] NONDESTRUCTIVE CLEAVAGE OF N-ACYLSULTAMS UNDER NEUTRAL CONDITIONS - PREPARATION OF ENANTIOMERICALLY, PURE FMOC-PROTECTED ALPHA-AMINO-ACIDS [J].

OPPOLZER, W ;

LIENARD, P .

HELVETICA CHIMICA ACTA, 1992, 75 (08) :2572-2582

[7] Anomalous mutarotation of salts of Reychler's acid VI Synthesis and structure of the sultam of 2-(N-methylamino)-d-camphane-10-sulfonic acid [J].

Shriner, RL ;

Shotton, JA ;

Sutherland, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1938, 60 :2794-2796

[8] SYNTHESIS OF MEDIUM AND LARGE RINGS .19. DETERMINATION OF THE ABSOLUTE-CONFIGURATIONS OF CHIRAL 3,6-HEXANOOXEPINES, [6]PARACYCLOPHANES, AND RELATED-COMPOUNDS [J].

TOCHTERMANN, W ;

OLSSON, G ;

VOGT, C ;

PETERS, EM ;

PETERS, K ;

VONSCHNERING, HG .

CHEMISCHE BERICHTE-RECUEIL, 1987, 120 (09) :1523-1532

[9]

Weismiller M. C., 1990, ORG SYNTH, V69, P154