BREAKDOWN OF HEMI-ORTHO-THIOAMIDE TETRAHEDRAL INTERMEDIATES

被引：25

作者：

KALOUSTIAN, MK

AGUILARLAURENTSDEGUTIERR.MI

NADER, RB

机构：

[1] Maria Isabel Aguilar-Laurents de Gutierrez

[2] Department of Chemistry, Fordham University, New York 10458, Bronx

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 04期

关键词：

D O I：

10.1021/jo01318a054

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The sulfhydrolyses of 2, N-dimethyl-1, 3-oxazolinium fluoroborate (1) and N, N-dimethyliminobutyrolactonium fluoroborate with anhydrous sodium hydrosulfide in solvent acetone at -78 °C were found to involve the preferential cleavage of the C-N bond rather than the C-O bond. © 1979, American Chemical Society. All rights reserved.

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页码：666 / 668

页数：3

相关论文

共 67 条

[1] On the addition of alkali alcholate to acidic ester. [J].

Adickes, F .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1925, 58 :1992-1999

[2] Concerning the deposition of alkali metal alcoholates on acid ester (II Announcement) [J].

Adickes, F .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1926, 59 :2522-2533

[3] PREDICTION OF STRENGTHS OF ORGANIC ACIDS [J].

BARLIN, GB ;

PERRIN, DD .

QUARTERLY REVIEWS, 1966, 20 (01) :75-&

[4] INTERMEDIATES IN THE REACTIONS OF CARBOXYLIC ACID DERIVATIVES .2. INFRARED ABSORPTION SPECTRA AS EVIDENCE FOR THE FORMATION OF ADDITION COMPOUNDS OF CARBOXYLIC ACID DERIVATIVES [J].

BENDER, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (23) :5986-5990

[5] OXYGEN EXCHANGE AS EVIDENCE FOR THE EXISTENCE OF AN INTERMEDIATE IN ESTER HYDROLYSIS [J].

BENDER, ML .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1951, 73 (04) :1626-1629

[6]

BENDER ML, 1971, MECHANISMS HOMOGENEO, P108

[7] SPECTROSCOPIC EVIDENCE FOR EXISTENCE OF A STABLE ACIDIC ORTHO-ESTER [J].

BLADON, P ;

FORREST, GC .

CHEMICAL COMMUNICATIONS, 1966, (14) :481-&

[8]

BOBRANSKI B, 1972, ROCZ CHEM, V46, P451

[9] ELECTRON-IMPACT STUDIES .88. FORMATION OF AN ADDUCT BETWEEN TRIFLUOROACETATE ANION AND PERFLUOROACETIC ANHYDRIDE BY ION-CYCLOTRON RESONANCE [J].

BOWIE, JH ;

WILLIAMS, BD .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1974, 27 (09) :1923-1927

[10]

BRANCH GEK, 1941, THEORY ORGANIC CHEM, P203

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