BREAKDOWN OF HEMI-ORTHO-THIOAMIDE TETRAHEDRAL INTERMEDIATES

被引:25
作者
KALOUSTIAN, MK
AGUILARLAURENTSDEGUTIERR.MI
NADER, RB
机构
[1] Maria Isabel Aguilar-Laurents de Gutierrez
[2] Department of Chemistry, Fordham University, New York 10458, Bronx
关键词
D O I
10.1021/jo01318a054
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The sulfhydrolyses of 2, N-dimethyl-1, 3-oxazolinium fluoroborate (1) and N, N-dimethyliminobutyrolactonium fluoroborate with anhydrous sodium hydrosulfide in solvent acetone at -78 °C were found to involve the preferential cleavage of the C-N bond rather than the C-O bond. © 1979, American Chemical Society. All rights reserved.
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收藏
页码:666 / 668
页数:3
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