CYCLOADDITION REACTIONS BETWEEN VINYLIDENE IRON(II) COMPLEXES AND ALKYNES - THE 1ST STABLE CYCLOBUTENYLIDENE COMPLEXES

被引：20

作者：

BAUER, D ^{[1
]}

HARTER, P ^{[1
]}

HERDTWECK, E ^{[1
]}

机构：

[1] TECH UNIV MUNICH,INST ANORGAN CHEM,LICHTENBERGSTR 4,W-8046 GARCHING,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 12期

关键词：

D O I：

10.1039/c39910000829

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[(eta-5-C5H5)(CO)LFe = C = CH2] + CF3SO3- complexes react with phenylpropyne with formation of [2 + 2] cycloadducts [(eta-5-C5H5)(CO)LFe = activated C-C(Me) = C(Ph)-CH2] + CF3SO3 - (structurally characterized by X-ray crystallography); addition of phenyllithium leads to a stable cyclobutenyl complex in good yield.

引用

页码：829 / 830

页数：2

共 9 条

[1] IRON(II) VINYLIDENES AND CHROMIUM CARBENE COMPLEXES IN BETA-LACTAM SYNTHESIS
BARRETT, AGM
MORTIER, J
SABAT, M
STURGESS, MA
[J]. ORGANOMETALLICS, 1988, 7 (12) : 2553 - 2561
[2] BERKE H, 1981, Z NATURFORSCH B, V36, P929
[3] SYNTHESIS AND CHARACTERIZATION OF CATIONIC IRON VINYLIDENE COMPOUNDS - FORMATION OF C-H, C-N, AND C-P BONDS AND THE X-RAY CRYSTAL-STRUCTURE OF [FE(ETA-C5H5)(CO)(PPH3)[C(PPH3)=CH2]]+BF-4
BOLANDLUSSIER, BE
CHURCHILL, MR
HUGHES, RP
RHEINGOLD, AL
[J]. ORGANOMETALLICS, 1982, 1 (04) : 628 - 634
[4] STABILITY OF THE CYCLOBUTENYL GROUP IN FE(C=CFCF2CF2)(CO)2(ETA-C5H5) TOWARDS ISOMERIZATION BY RING-OPENING - X-RAY CRYSTAL-STRUCTURES OF FE(C=CFCF2CF2)(CO)(CO)(ETA-C5H5), FE(C=CFCF2CF2)(CO)(PPH3)(ETA-C5H5)
BRUCE, MI
LIDDELL, MJ
SNOW, MR
TIEKINK, ERT
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 354 (01) : 103 - 115
[5] REACTIVITY AND CONFORMATION OF A PHOSPHINE-SUBSTITUTED DIHALOCARBENE COMPLEX - X-RAY CRYSTAL-STRUCTURES OF [(ETA-5-C5H5)FE(CO)(PPH3)(CF2)][BF4] AND [(ETA-5-C5H5)FE(CO)2(CCL2)][BCL4]
CRESPI, AM
SHRIVER, DF
[J]. ORGANOMETALLICS, 1985, 4 (10) : 1830 - 1835
[6] FORMATION OF A TUNGSTEN VINYLVINYLIDENE COMPLEX FROM ADDITION OF ALKYNE TO (DPPE)(OC)3W=C=CHPH
GAMBLE, AS
BIRDWHISTELL, KR
TEMPLETON, JL
[J]. ORGANOMETALLICS, 1988, 7 (05) : 1046 - 1050
[7] COMPLEX CHEMISTRY OF REACTIVE ORGANIC-COMPOUNDS .46. CONFORMATION OF METAL CARBENE COMPLEXES - SYNTHESIS AND STRUCTURE OF (ETA-5-C5H5)CR(CO)(NO)[C(C6H5)2] AND ITS RELATIONSHIP TO THE ISOELECTRONIC COMPOUND (ETA-5-C5H5)MN(CO)2[C(C6H5)2]
HERRMANN, WA
HUBBARD, JL
BERNAL, I
KORP, JD
HAYMORE, BL
HILLHOUSE, GL
[J]. INORGANIC CHEMISTRY, 1984, 23 (19) : 2978 - 2983
[8] EFFECT OF LIGAND ASYMMETRY ON THE STRUCTURE AND REACTIVITY OF CPMLL'(ALLYL) AND CPMLL'(ETHYLENE) COMPLEXES
SCHILLING, BER
HOFFMANN, R
FALLER, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (03) : 592 - 598
[9] CPM(CO)2(LIGAND) COMPLEXES
SCHILLING, BER
HOFFMANN, R
LICHTENBERGER, DL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (03) : 585 - 591

← 1 →