SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE 1ST STABLE DIARYLLEAD(II) COMPOUND

被引：106

作者：

BROOKER, S ^{[1
]}

BUIJINK, JK ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 01期

关键词：

D O I：

10.1021/om00047a014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of PbCl2 with 2,4,6-(CF3)3C6H2Li results in the formation of the first stable diarylead(II) compound, [2,4,6-(CF3)3C6H2]2Pb (4). X-ray structural analysis shows that in the solid state 4 is a bent monomer. 4 reacts with 2,4,6-(CF3)3C6H2SH (5) in hydrocarbon solutions to produce the solvent-free thiolate [2,4,6-(CF3)3C6H2S]2Pb (6).

引用

页码：25 / 26

页数：2

共 16 条

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