PRESSURE EFFECTS ON EQUILIBRATION KINETICS OF RHCLN(OH2)6-N(N-3)-SPECIES FOR N = 4, 5, 6 IN ACIDIC AQUEOUS-SOLUTION

被引：24

作者：

HYDE, KE ^{[1
]}

KELM, H ^{[1
]}

PALMER, DA ^{[1
]}

机构：

[1] UNIV FRANKFURT,DEPT PHYS CHEM,D-6000 FRANKFURT,FED REP GER

来源：

INORGANIC CHEMISTRY | 1978年 / 17卷 / 06期

关键词：

D O I：

10.1021/ic50184a052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rates of equilibration of the RhCl63-, RhCl5(OH2)2-, and cis-RhCl4(OH2)2- ions were studied as a function of chloride ion concentration and pressure (1-1500 bar) at 20 °C and n = 4 M (HC104). ΔFV‡ values for the aquation of the hexachloro and pentachloro species are 21.5 ± 0.6 and 14.3 ± 0.5 cm3 mol-1. For the chloride anation of the pentachloro and tetrachloro species ΔV‡exptl are 15.7 ± 6.5 and 14.7 ± 1.6 cm3 mol-1. These results are discussed in terms of a dissociative mechanism. © 1978, American Chemical Society. All rights reserved.

引用

页码：1647 / 1649

页数：3

共 25 条

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