MOLECULAR-WEIGHT AND HG-199 NMR-STUDIES ON MERCURY-RICH CATIONS PRODUCED FROM MERCURY(II) DITHIOCARBAMATES

被引：9

作者：

BOND, AM ^{[1
]}

HOLLENKAMP, AF ^{[1
]}

COLTON, R ^{[1
]}

MCGREGOR, K ^{[1
]}

机构：

[1] UNIV MELBOURNE,DEPT INORGAN CHEM,PARKVILLE,VIC 3052,AUSTRALIA

来源：

INORGANICA CHIMICA ACTA | 1990年 / 168卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80948-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mercury-rich dithiocarbamate cations [Hg3(R2dtc)4]2+ and [Hg4(pipdtc)6]2+ (R = Et, Bz; pip = piperidyl; dtc = dithiocarbamate) have been shown by a polarographic method to be partially dissociated at the \R~2 × 10-4 M concentration level in dichloromethane solution. However, for approximately 10-2 M solutions of [Hg3(R2dtc)4]2+ in dichloromethane, mercury-199 NMR studies over a wide temperature range are more consistent with the presence of higher oligomers such as [Hg6(R2dtc)8]4+. © 1990.

引用

页码：233 / 236

页数：4

共 20 条

[1]

ABRAHAMS BF, COMMUNICATION

[2] EXAMINATION OF MERCURY DITHIOCARBAMATE TRIALKYLPHOSPHINE MIXED-LIGAND COMPLEXES BY ELECTROCHEMICAL TECHNIQUES AT MERCURY-ELECTRODES AND MULTINUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY [J].

BOND, AM ;

COLTON, R ;

HOLLENKAMP, AF ;

MOIR, JE .

INORGANIC CHEMISTRY, 1986, 25 (10) :1519-1526

[3] P-31, CD-113 AND HG-199 NMR-STUDIES ON DITHIOLATE COMPLEXES OF CADMIUM AND MERCURY AND THEIR PHOSPHINE ADDUCTS [J].

BOND, AM ;

COLTON, R ;

DAKTERNIEKS, D ;

DILLON, ML ;

HAUENSTEIN, J ;

MOIR, JE .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1981, 34 (07) :1393-1400

[4] INVESTIGATION OF EXCHANGE AND REDOX REACTIONS OF MERCURY DITHIOCARBAMATE COMPLEXES BY ELECTROCHEMICAL TECHNIQUES AT MERCURY-ELECTRODES, HG-199 NUCLEAR MAGNETIC-RESONANCE SPECTROMETRY, AND MASS-SPECTROMETRY [J].

BOND, AM ;

COLTON, R ;

DILLON, ML ;

MOIR, JE ;

PAGE, DR .

INORGANIC CHEMISTRY, 1984, 23 (18) :2883-2891

[5] REVERSIBLE ELECTRODE PROCESSES INVOLVING MULTISTEP MECHANISMS FOR CADMIUM DITHIOCARBAMATES AND DISELENOCARBAMATES AT MERCURY-ELECTRODES [J].

BOND, AM ;

COLTON, R ;

DILLON, ML ;

HOLLENKAMP, AF ;

MOIR, JE .

INORGANIC CHEMISTRY, 1985, 24 (10) :1591-1597

[6] VOLTAMMETRIC, COULOMETRIC, HG-199 NMR, AND OTHER STUDIES CHARACTERIZING NEW AND UNUSUAL MERCURY COMPLEXES PRODUCED BY ELECTROCHEMICAL OXIDATION OF MERCURY(II) DIETHYLDITHIOCARBAMATE - CRYSTAL AND MOLECULAR-STRUCTURE OF OCTAKIS(N,N-DIETHYLDITHIOCARBAMATO)PENTAMERCURY(II) PERCHLORAT [J].

BOND, AM ;

COLTON, R ;

HOLLENKAMP, AF ;

HOSKINS, BF ;

MCGREGOR, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (07) :1969-1980

[7]

BOND AM, UNPUB J AM CHEM SOC

[8] A CRYSTALLOGRAPHIC AND SPECTROSCOPIC STUDY OF MERCURY(II) DITHIOCARBAMATE [J].

CHIEH, C ;

CHEUNG, SK .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1981, 59 (18) :2746-2749

[9]

Coucouvanis D., 1979, PROG INORG CHEM, V26, P301, DOI [10.1002/9780470166277.ch5, DOI 10.1002/9780470166277.CH5]

[10]

COUCOUVANIS D, 1970, PROG INORG CHEM, V11, P2303

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