OPTIMAL PEAK SEPARATION DERIVED FROM INFORMATION-THEORY OF CHROMATOGRAPHY

被引：15

作者：

HAYASHI, Y

机构：

[1] Section of Instrumental Analysis, National Institute of Hygienic Sciences, Tokyo 158, Kamiyoga, Setagaya

来源：

ANALYTICAL SCIENCES | 1990年 / 6卷 / 02期

关键词：

chromatography; FUMI; information theory; Kalman filter; Optimization;

D O I：

10.2116/analsci.6.257

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The optimal separation of peaks in column chromatography is derived from information theory based on FUMI. The optimal is shown to be described by the chromatographic resolution Rs. The information theory of column chromatography demonstrates that optimization based on FUMI can entail optimization on Rs as a special case. The peak capacity can also be derived theoretically from FUMI. © 1990, The Japan Society for Analytical Chemistry. All rights reserved.

引用

收藏

页码：257 / 260

页数：4

相关论文

共 22 条

[1]

ARIMOTO S, 1976, JOHOU RIRON

[2] A CRITICAL-EVALUATION OF QUALITY CRITERIA FOR THE OPTIMIZATION OF CHROMATOGRAPHIC MULTICOMPONENT SEPARATIONS [J].

DEBETS, HJG ;

BAJEMA, BL ;

DOORNBOS, DA .

ANALYTICA CHIMICA ACTA, 1983, 151 (01) :131-141

[3] MAXIMUM NUMBER OF COMPONENTS RESOLVABLE BY GEL FILTRATION AND OTHER ELUTION CHROMATOGRAPHIC METHODS [J].

GIDDINGS, JC .

ANALYTICAL CHEMISTRY, 1967, 39 (08) :1027-&

[4] OPTIMIZATION OF SELECTIVITY IN HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY USING MIXTURE-DESIGN STATISTICAL TECHNIQUES - OVERVIEW AND SOFTWARE FOR DATA-ANALYSIS [J].

GLAJCH, JL ;

KIRKLAND, JJ ;

MINOR, JM .

JOURNAL OF LIQUID CHROMATOGRAPHY, 1987, 10 (8-9) :1727-1747

[5]

GOEWIE CE, 1985, J LIQ CHROMATOGR, V9, P1431

[6] ONE-DIMENSIONAL KALMAN FILTER IN A ROBOT SYSTEM FOR TOTAL ANALYSIS OF SOLID DOSAGE FORMULATIONS [J].

HAYASHI, Y ;

MATSUDA, R ;

YOSHIOKA, S ;

TAKEDA, Y .

ANALYTICA CHIMICA ACTA, 1988, 209 (1-2) :45-55

[7] OPTIMIZATION OF DETECTION WAVELENGTHS IN LIQUID-CHROMATOGRAPHY ON THE BASIS OF INFORMATION-THEORY AND KALMAN FILTER [J].

HAYASHI, Y ;

MATSUDA, R .

ANALYTICAL SCIENCES, 1989, 5 (04) :459-464

[8] A ONE-DIMENSIONAL KALMAN FILTER FOR PEAK RESOLUTION [J].

HAYASHI, Y ;

YOSHIOKA, S ;

TAKEDA, Y .

ANALYTICA CHIMICA ACTA, 1988, 212 (1-2) :81-94

[9]

HAYASHI Y, 1990, ANAL SCI, V6, P15, DOI 10.2116/analsci.6.15

[10] MODIFICATION OF THE FUNCTION OF MUTUAL INFORMATION BASED ON INFORMATION-THEORY AND THE KALMAN FILTER FOR CHROMATOGRAPHIC OPTIMIZATION [J].

HAYASHI, Y ;

MATSUDA, R .

ANALYTICA CHIMICA ACTA, 1989, 222 (02) :313-322