2-TRIMETHYLSILYLETHYL-1,3-BUTADIENE AS A SYNTHETIC EQUIVALENT OF PARENT CROSS-CONJUGATED HEXATRIENE, 3-METHYLENE-1,4-PENTADIENE

被引：16

作者：

HOSOMI, A ^{[1
]}

MASUNARI, T ^{[1
]}

TOMINAGA, Y ^{[1
]}

YANAGI, T ^{[1
]}

HOJO, M ^{[1
]}

机构：

[1] NAGASAKI UNIV, FAC PHARMACEUT SCI, NAGASAKI 852, JAPAN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 43期

关键词：

D O I：

10.1016/S0040-4039(00)97024-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

2-Trimethylsilylethyl-1,3-butadiene, readily prepared by the cross-coupling reaction of the Grignard reagent of 3-bromo-3-butenyltrimethylsilane with vinyl bromide catalyzed by a nickel-phosphine complex, works as a synthetic equivalent to 3-methylene-1,4-pentadiene (parent [3]dendralene) by the consecutive Diels-Alder reactions. © 1990.

引用

页码：6201 / 6204

页数：4

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