DETERMINATION OF HYDROGEN-PEROXIDE BY FLOW-INJECTION ANALYSIS WITH ARYL OXALATE-SULFORHODAMINE-101 CHEMILUMINESCENCE

被引：20

作者：

KATAYAMA, M

TAKEUCHI, H

TANIGUCHI, H

机构：

[1] Meiji College of Pharmacy, Setagaya-ku, Tokyo, 154

来源：

ANALYTICAL LETTERS | 1991年 / 24卷 / 06期

关键词：

CHEMILUMINESCENCE; SULFORHODAMINE-101; HYDROGEN PEROXIDE; ARYL OXALATE; FLOW INJECTION ANALYSIS; TDPO;

D O I：

10.1080/00032719108054370

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A flow injection analysis (FIA) method for the determination of hydrogen peroxide by aryl oxalate chemiluminescence detection was studied. The analyte was detected by using sulforhodamine 101 as a new fluorophore and bis[4-nitro-2-(3,6,9-trioxadecyloxycarbonyl)phenyl]oxalate (TDPO) in imidazole buffer (pH 7.0)-acetonitrile. The detection limit was 3.0 x 10(-9) M. The relative standard deviation (n = 6) for 1.0 x 10(-6) M hydrogen peroxide was 2.8 %. This FIA method was shown to be 20 to 2500 times more sensitive than the previous FIA method with aryl oxalate chemiluminescence.

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页码：1005 / 1015

页数：11

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共 22 条

[1] NATIVE PEROXYOXALATE CHEMILUMINESCENCE FROM THE REACTION OF BIS(2,4-DINITROPHENYL) OXALATE AND HYDROGEN-PEROXIDE PERTURBED BY NONFLUOROPHORES [J].

CAPOMACCHIA, AC ;

JENNINGS, RN ;

HEMINGWAY, SM ;

DSOUZA, P ;

PRAPAITRAKUL, W ;

GINGLE, A .

ANALYTICA CHIMICA ACTA, 1987, 196 :305-310

[2] IMMOBILIZED FLUOROPHORES IN DYNAMIC CHEMI-LUMINESCENCE DETECTION OF HYDROGEN-PEROXIDE [J].

GUBITZ, G ;

VANZOONEN, P ;

GOOIJER, C ;

VELTHORST, NH ;

FREI, RW .

ANALYTICAL CHEMISTRY, 1985, 57 (11) :2071-2074

[3] EVALUATION OF FLUORESCENT COMPOUNDS FOR PEROXYOXALATE CHEMILUMINESCENCE DETECTION [J].

HONDA, K ;

MIYAGUCHI, K ;

IMAI, K .

ANALYTICA CHIMICA ACTA, 1985, 177 :111-120

[4] IMMOBILIZED LUMINOL CHEMI-LUMINESCENCE REAGENT SYSTEM FOR HYDROGEN-PEROXIDE DETERMINATIONS IN FLOWING STREAMS [J].

HOOL, K ;

NIEMAN, TA .

ANALYTICAL CHEMISTRY, 1988, 60 (09) :834-837

[5] NOVEL ARYL OXALATE ESTERS FOR PEROXYOXALATE CHEMILUMINESCENCE REACTIONS [J].

IMAI, K ;

NAWA, H ;

TANAKA, M ;

OGATA, H .

ANALYST, 1986, 111 (02) :209-211

[6] APPLICATION OF BIS[4-NITRO-2-(3,6,9-TRIOXADECYLOXYCARBONYL)-PHENYL]OXALATE TO POSTCOLUMN CHEMILUMINESCENCE DETECTION IN HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY [J].

IMAI, K ;

MATSUNAGA, Y ;

TSUKAMOTO, Y ;

NISHITANI, A .

JOURNAL OF CHROMATOGRAPHY, 1987, 400 :169-176

[7] DETERMINATION OF CATECHOLAMINES WITH LUCIGENIN CHEMI-LUMINESCENCE [J].

KAMIDATE, T ;

YOSHIDA, K ;

SEGAWA, T ;

WATANABE, H .

ANALYTICAL SCIENCES, 1989, 5 (03) :359-360

[8] DETERMINATION OF FLUORESCENT COMPOUNDS BY HIGH-PERFORMANCE LIQUID-CHROMATOGRAPHY WITH CHEMI-LUMINESCENCE DETECTION [J].

KOBAYASHI, S ;

IMAI, K .

ANALYTICAL CHEMISTRY, 1980, 52 (03) :424-427

[9] DETERMINATION OF TRACE LEVELS OF STEROIDS IN BLOOD-PLASMA BY LIQUID-CHROMATOGRAPHY WITH PEROXYOXALATE CHEMI-LUMINESCENCE DETECTION [J].

KOZIOL, T ;

GRAYESKI, ML ;

WEINBERGER, R .

JOURNAL OF CHROMATOGRAPHY, 1984, 317 (DEC) :355-366

[10] RHODAMINE LABELING REAGENT FOR THE DETERMINATION OF CHLOROPHENOLS BY LIQUID-CHROMATOGRAPHY WITH PEROXYOXALATE CHEMI-LUMINESCENCE DETECTION [J].

KWAKMAN, PJM ;

MOL, JGJ ;

KAMMINGA, DA ;

FREI, RW ;

BRINKMAN, UAT ;

DEJONG, GJ .

JOURNAL OF CHROMATOGRAPHY, 1988, 459 :139-149