THE CHIRAL CATALYST CONTROL - A SIGNIFICANT ROLE OF A CHIRAL CATALYST IN THE DIASTEREOSELECTIVE ALDOL REACTION USING CHIRAL ALDEHYDES

被引：36

作者：

KOBAYASHI, S

OHTSUBO, A

MUKAIYAMA, T

机构：

来源：

CHEMISTRY LETTERS | 1991年 / 05期

关键词：

D O I：

10.1246/cl.1991.831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The stereochemistry in the aldol reaction of a silyl enol ether with chiral aldehydes is almost completely controlled by the chiral catalyst regardless of the inherent diastereofacial preference of the chiral aldehydes.

引用

页码：831 / 834

页数：4

共 15 条

[1] ANH NT, 1977, NOUV J CHIM, V1, P61
[2] Cherest M., 1968, TETRAHEDRON LETT, P2199
[3] STUDIES IN STEREOCHEMISTRY .10. THE RULE OF STERIC CONTROL OF ASYMMETRIC INDUCTION IN THE SYNTHESES OF ACYCLIC SYSTEMS
CRAM, DJ
ELHAFEZ, FAA
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (23) : 5828 - 5835
[4] HEATHCOCK CH, 1984, ASYMMETRIC SYNTHESIS, V3, P111
[5] ASYMMETRIC INDUCTION . A MODEL FOR ADDITIONS TO CARBONYLS DIRECTLY BONDED TO ASYMMETRIC CARBONS
KARABATS.GJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (06) : 1367 - &
[6] ASYMMETRIC ALDOL-TYPE REACTION BETWEEN BOTH ACHIRAL KETENE SILYL ACETALS AND ALDEHYDES BY THE USE OF A CHIRAL PROMOTER
KOBAYASHI, S
SANO, T
MUKAIYAMA, T
[J]. CHEMISTRY LETTERS, 1989, (08) : 1319 - 1322
[7] THE EFFICIENT CATALYTIC ASYMMETRIC ALDOL-TYPE REACTION
KOBAYASHI, S
FUJISHITA, Y
MUKAIYAMA, T
[J]. CHEMISTRY LETTERS, 1990, (08) : 1455 - 1458
[8] A HIGHLY ENANTIOSELECTIVE SYNTHESIS OF 2-SUBSTITUTED MALATES BY ASYMMETRIC ALDOL REACTION
KOBAYASHI, S
FUJISHITA, Y
MUKAIYAMA, T
[J]. CHEMISTRY LETTERS, 1989, (11) : 2069 - 2072
[9] ASYMMETRIC ALDOL REACTION OF SILYL ENOL ETHERS WITH ALDEHYDES PROMOTED BY THE COMBINED USE OF CHIRAL DIAMINE COORDINATED TIN(II) TRIFLATE AND TRIBUTYLTIN FLUORIDE
KOBAYASHI, S
MUKAIYAMA, T
[J]. CHEMISTRY LETTERS, 1989, (02) : 297 - 300
[10] PERFECT STEREOCHEMICAL CONTROL IN THE SYNTHESIS OF SYN-ALPHA-METHYL-BETA-HYDROXY THIOESTERS BY ASYMMETRIC ALDOL REACTION OF SILYL ENOL ETHERS WITH ALDEHYDES
MUKAIYAMA, T
UCHIRO, H
KOBAYASHI, S
[J]. CHEMISTRY LETTERS, 1989, (06) : 1001 - 1004

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