REACTIONS OF ELECTROCHEMICALLY GENERATED ORGANOMETALLICS .5. SYNTHESIS OF SUBSTITUTED BETA-LACTONES BY A REFORMATSKY REACTION OF CARBONYL-COMPOUNDS, PHENYL ALPHA-BROMOALKANOATES, AND INDIUM

被引：23

作者：

SCHICK, H

LUDWIG, R

KLEINER, K

KUNATH, A

机构：

[1] Institut für Angewandte Chemie Berlin-Adlershof e. V., D-12489 Berlin

来源：

TETRAHEDRON | 1995年 / 51卷 / 10期

关键词：

D O I：

10.1016/0040-4020(95)00039-B

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Di-, tri-, and tetrasubstituted beta-lactones are accessible in a one-step procedure by a Reformatsky reaction of phenyl alpha-bromoalkanoates with ketones or aldehydes at a sacrificial indium anode. With indium powder comparable results are obtained. The yield of beta-lactones is significantly lower, if zinc is used instead of indium.

引用

页码：2939 / 2946

页数：8

共 24 条

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