ALIPHATIC HYDROXY-ACIDS .3. SYNTHESES WITH ALKYL 2-ACETOXY-3-CARBOXYPROPIONATES

被引：17

作者：

BRETTLE, R

LATHAM, DW

机构：

[1] Department of Chemistry, The University, Sheffield

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1968年 / 08期

关键词：

D O I：

10.1039/j39680000906

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyl (±)-2-acetoxy-3-carboxypropionate has been prepared from (±)-malic acid and used in crossed Kolbe electrolyses to prepare dimethyl (±)-2-acetoxydodecane-1,12-dioate and three methyl 2-acetoxyalkanoates. Dimethyl and diethyl meso-2,5-diacetoxyadipates have been isolated from the Kolbe electrolyses of methyl and ethyl (±)-2-acetoxy-3-carboxypropionates respectively, and the presence of the corresponding (±)-2,5- diacetoxyadipates has been established. Lithium aluminium hydride reduction of diethyl meso-2,5-diacetoxyadipate gives meso-hexane-1,2,5,6-tetraol.

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页码：906 / &

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