NON-LINEAR INTENSITY DEPENDENCE OF THE RATE COEFFICIENT IN UNIMOLECULAR REACTIONS INDUCED BY MONOCHROMATIC INFRARED RADIATION

被引：23

作者：

QUACK, M

机构：

[1] Institut für Physikalische Chemie der Universität

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 65卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80144-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

It is shown that essentially incoherent, stepwise one-photon transitions arising in dense multilevel structures of polyatomic molecules irradiated with monochromatic coherent infrared radiation can give rise (under specified conditions) to a more than proportional intensity dependence of the steady-state rate coefficient in unimolecular reactions induced by monochromatic infrared radiation. © 1979.

引用

页码：140 / 145

页数：6

共 33 条

[1] SELECTIVE DISSOCIATION OF POLYATOMIC-MOLECULES BY INTENSE INFRARED-LASER FIELDS [J].