ELECTROPHILIC CLEAVAGE OF C-F BONDS IN HYDRIDO TRIFLUOROMETHYL COMPLEXES OF PLATINUM(II) BY PROTON ACIDS - SYNTHESIS OF HYDRIDO CARBENE AND HYDRIDO CARBONYL DERIVATIVES AND X-RAY STRUCTURES OF TRANS-PTH(CF3)(PPH3)2 (180 K) AND TRANS-[PTH(COCH2CH2O)(PPH3)2]BF4 (298 K)

被引：68

作者：

MICHELIN, RA

ROS, R

GUADALUPI, G

BOMBIERI, G

BENETOLLO, F

CHAPUIS, G

机构：

[1] UNIV PADUA,IST CHIM IND,I-35100 PADUA,ITALY

[2] CNR,IST CHIM & TECNOL RADIOELEMENTI,I-35100 PADUA,ITALY

[3] UNIV MILANO,IST CHIM FARMACEUT,I-20131 MILANO,ITALY

[4] INST CRISTALLOG,CH-1005 LAUSANNE,SWITZERLAND

来源：

INORGANIC CHEMISTRY | 1989年 / 28卷 / 05期

关键词：

D O I：

10.1021/ic00304a009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：840 / 846

页数：7

共 56 条

[1]

Andreassen A.L., 1971, J CHEM PHYS, V56, P3802

[2]

[Anonymous], 1969, ORGANIC FLUORINE CHE

[3] TRANS-INFLUENCE - ITS MEASUREMENT AND SIGNIFICANCE [J].

APPLETON, TG ;

CLARK, HC ;

MANZER, LE .

COORDINATION CHEMISTRY REVIEWS, 1973, 10 (3-4) :335-422

[4] PREPARATION OF SOME HYDRIDOTRICYCLOHEXYLPHOSPHINE PLATINUM(II) COMPLEXES [J].

ATTIG, TG ;

CLARK, HC .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1975, 53 (22) :3466-3470

[5] SYNTHESIS OF BIS-MU-DIORGANOSILANEDIYL-AF-DIHYDRIDOBIS(TRIORGANOPHOSPHINE)DIPLATINUM COMPLEXES - CRYSTAL AND MOLECULAR-STRUCTURE OF [(PTH(MU-SIME2)[P(C6H11)3])2] [J].

AUBURN, M ;

CIRIANO, M ;

HOWARD, JAK ;

MURRAY, M ;

PUGH, NJ ;

SPENCER, JL ;

STONE, FGA ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1980, (04) :659-666

[6] COMPOUNDS CONTAINING PLATINUM-CARBON BONDS .7. CRYSTAL AND MOLECULAR-STRUCTURE OF CIS[ANILINO(ETHOXY)CARBENE]DICHLORO(TRIETHYL-PHOSPHINE)PLATINUM(II) [J].

BADLEY, EM ;

MUIR, KW ;

SIM, GA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (19) :1930-1933

[7] COMPARISON OF ORTHO-ALKYL AND ORTHO-PERFLUOROALKYL GROUPS AS LIGANDS .2. CRYSTAL AND MOLECULAR-STRUCTURES OF DIMETHYL[(2-VINYLPHENYL)DIPHENYLPHOSPHINE]PLATINUM(II) AND BIS(TRIFLUOROMETHYL)[(2-VINYLPHENYL)DIPHENYLPHOSPHINE]PLATINUM(II) [J].

BENNETT, MA ;

CHEE, HK ;

JEFFERY, JC ;

ROBERTSON, GB .

INORGANIC CHEMISTRY, 1979, 18 (04) :1071-1076

[8] COMPARISON OF ORTHO-ALKYL AND ORTHO-PERFLUOROALKYL GROUPS AS LIGANDS .1. CRYSTAL AND MOLECULAR-STRUCTURES OF THE METHYLPLATINUM(II), (TRIFLUOROMETHYL)PLATINUM(II), AND (PENTAFLUOROETHYL)PLATINUM(II) COMPLEXES TRANS-PTCIR(PMEPH2)2 (R = CH3, CF3, C2F5) [J].

BENNETT, MA ;

CHEE, HK ;

ROBERTSON, GB .

INORGANIC CHEMISTRY, 1979, 18 (04) :1061-1070

[9] TRANSITION METAL-CARBENE COMPLEXES [J].

CARDIN, DJ ;

CETINKAY.B ;

LAPPERT, MF .

CHEMICAL REVIEWS, 1972, 72 (05) :545-+

[10]

CETINKAYA B, 1973, J CHEM SOC DALTON, P906

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