REACTIONS OF DICHLOROCARBENE WITH OLEFINS . TEMPERATURE DEPENDENCE OF RELATIVE REACTIVITIES

被引：164

作者：

SKELL, PS

CHOLOD, MS

机构：

[1] Department of Chemistry, Pennsylvania State University, University Park

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 25期

关键词：

D O I：

10.1021/ja01053a040

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Relative rates of addition of CCl2 to olefins were determined between 0 and –80°. Relative olefin reactivities were found to vary with temperature, but were independent of the method of CCI2 generation. Activation parameters were determined for the addition reaction. The olefin-CCl2 addition mechanism and the relation of CCl2 to other electrophilic species are discussed. © 1969, American Chemical Society. All rights reserved.

引用

收藏

页码：7131 / &

相关论文

共 21 条

[1] REDUCED CYCLIC COMPOUNDS .5. THE PREPARATION OF 5-6-DIHYDRO-3-METHYL-4H-PYRAN AND ITS CONVERSION INTO 4-METHYL-HEX-TRANS-4-EN-1-OL [J].

ANSELL, MF ;

GADSBY, B .

JOURNAL OF THE CHEMICAL SOCIETY, 1958, (OCT) :3388-3397

[2] NUCLEOPHILIC REACTIVITY OF CARBON-CARBON DOUBLE BOND .2. SOLVOLYTIC RING CLOSURE OF 2-(3-METHYL- AND 3,4-DIMETHYL-DELTA3-CYCLOPENTENYL)ETHYL P-NITROBENZENESULFONATES [J].

BARTLETT, PD ;

SARGENT, GD .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (06) :1297-+

[3] TEMPERATURE DEPENDENCE OF THE RATES OF ADDITION OF OXYGEN ATOMS TO OLEFINS [J].

CVETANOVIC, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1960, 33 (04) :1063-1068

[4] ELECTROPHILIC CHARACTER OF OXYGEN ATOMS [J].

CVETANOVIC, RJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1960, 38 (10) :1678-1687

[5]

DOERING WVE, 1956, J AM CHEM SOC, V78, P3224

[6]

DOERING WVE, 1958, J AM CHEM SOC, V80, P5274

[7]

FARINA M, 1960, CHIM IND-MILAN, V42, P967

[8] THE EFFECT OF STRUCTURE ON THE RELATIVE STABILITY OF DIHALOMETHYLENES [J].

HINE, J ;

EHRENSON, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (04) :824-830

[9] TRIMETHYLENE AND ADDITION OF METHYLENE TO ETHYLENE [J].

HOFFMANN, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1968, 90 (06) :1475-&

[10] REACTIONS OF CHELATED ORGANOLITHIUM COMPOUNDS [J].

LANGER, AW .

TRANSACTIONS OF THE NEW YORK ACADEMY OF SCIENCES, 1965, 27 (07) :741-&