STOICHIOMETRIC DEHYDROGENATION OF CYCLIC ALKENES WITHOUT HYDROGEN ACCEPTORS USING THE '(C5ME5)RU+' FRAGMENT - X-RAY CRYSTAL-STRUCTURE OF [(ETA-5-C5ME5)RU-(MU-2,ETA-5,ETA-5-C5ME4OH)-RU(ETA-5-C5ME5)]CF3SO3.CH2CL2

被引：15

作者：

CHAUDRET, B ^{[1
]}

DAHAN, F ^{[1
]}

HE, XD ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1990年 / 16期

关键词：

D O I：

10.1039/c39900001111

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

引用

页码：1111 / 1113

页数：3

共 23 条

[1] UNEXPECTED DEHYDROGENATION OF A CYCLOHEXYL GROUP AT LOW-TEMPERATURE THROUGH PROTONATION OF RUH3(ETA-5-C5ME5)(PCY3) (CY = CYCLOHEXYL) - X-RAY STRUCTURE OF [(ETA-5-C5ME5)RU((C6H9)P(C6H11))2]BF4 [J].

ARLIGUIE, T ;

CHAUDRET, B ;

JALON, F ;

LAHOZ, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (15) :998-1000

[2] THE SELECTIVE CATALYTIC CONVERSION OF CYCLOALKANES INTO CYCLOALKENES USING A SOLUBLE RHENIUM POLYHYDRIDE SYSTEM [J].

BAUDRY, D ;

EPHRITIKHINE, M ;

FELKIN, H ;

HOLMESSMITH, R .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (14) :788-789

[3]

BOUACHIR F, 1987, NEW J CHEM, V11, P527

[4] [RUH(1-6-ETA-C8H10)(1',2'-5',6'-ETA-C8H12)]BF4, THE 1ST ISOLATED HYDRIDOMETAL COMPLEX STABILIZED ONLY BY ALICYCLIC HYDROCARBON LIGANDS AND A VERY EFFICIENT CATALYST PRECURSOR FOR THE TRANSFORMATION OF ALKENES [J].

BOUACHIR, F ;

CHAUDRET, B ;

TKATCHENKO, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (02) :94-96

[5] ALKANE FUNCTIONALIZATION ON A PREPARATIVE SCALE BY MERCURY-PHOTOSENSITIZED CROSS-DEHYDRODIMERIZATION [J].

BROWN, SH ;

CRABTREE, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) :2946-2953

[6] SELECTIVE CATALYTIC DEHYDROGENATION OF ALKANES TO ALKENES [J].

BURK, MJ ;

CRABTREE, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) :8025-8032

[7] SELECTIVE PREPARATION OF UNUSUAL PI-ADDUCTS OF THE FUNCTIONAL ARENES DIPHENYLACETYLENE, PHENOL, AND BENZOIC-ACID WITH THE CPRU+ FRAGMENT (CP = C5ME5) [J].

CHAUDRET, B ;

HE, XD ;

HUANG, YS .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (23) :1844-1846

[8] REACTIONS BETWEEN BIS(STYRENE)BIS(TRIPHENYLPHOSPHINE)-RUTHENIUM(0) AND CYCLOHEXENE - ITS RELEVANCE TO ALKENE ISOMERIZATION REACTION AND TO CATALYTIC DISPROPORTIONATION OF CYCLOHEXENE [J].

CHAUDRET, BN ;

COLEHAMILTON, DJ ;

WILKINSON, G .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1978, 32 (08) :763-769

[9] THE ORGANOMETALLIC CHEMISTRY OF ALKANES [J].

CRABTREE, RH .

CHEMICAL REVIEWS, 1985, 85 (04) :245-269

[10] ARENE AND CYCLOHEXADIENYL COMPLEXES AS INTERMEDIATES IN THE SELECTIVE CATALYTIC DEHYDROGENATION OF CYCLOHEXENES TO ARENES [J].

CRABTREE, RH ;

PARNELL, CP .

ORGANOMETALLICS, 1985, 4 (03) :519-523

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