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ANOMALOUS AUGER SHIFTS IN CHEMISORPTION ON TUNGSTEN

被引：5
作者：
FOULIAS, SD
RAWLINGS, KJ
HOPKINS, BJ
机构：
[1] Surface Physics, University of Southampton, Southampton
来源：
CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期
关键词：
D O I：
10.1016/0009-2614(79)80073-1
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Substrate Auger line energy shifts for monolayer gas adsorption are readily detected. The observed shifts in tungsten are incompatible with predicted chemical-shift trends and hence relaxation effects must be considered. It is proposed that transition-metal s electrons play a decisive role in core-hole screening. The measurement of substrate Auger line energy shifts on gas adsorption may thus provide information on the contribution of these electrons to chemisorption. © 1979.
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页码：81 / 85
页数：5
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