SYNTHESIS AND STRUCTURE OF A NOVEL LARGE-PORE MICROPOROUS MAGNESIUM-CONTAINING ALUMINOPHOSPHATE (DAF-1)

被引：74

作者：

WRIGHT, PA

JONES, RH

NATARAJAN, S

BELL, RG

CHEN, JS

HURSTHOUSE, MB

THOMAS, JM

机构：

[1] UNIV WALES COLL CARDIFF, SCH CHEM & APPL CHEM, CARDIFF CF1 3XA, WALES

[2] UNIV KEELE, DEPT CHEM, KEELE ST5 5BG, STAFFS, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 07期

关键词：

D O I：

10.1039/c39930000633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mg0.22Al0.78PO4.0.12(C16H38N2).xH2O crystallizes during hydrothermal synthesis into a unique extended three-dimensional (3-D) tetrahedrally-coordinated framework structure possessing two parallel channel systems with approximately circular aperture openings of ca. 6.1 and 7.5 angstrom respectively,the latter of which contains supercages 16.3 angstrom in diameter: these large pores are linked perpendicularly by two types of interconnecting apertures, the minimum diameter of one of which is ca. 3.9 and that of the other 5.4 angstrom

引用

页码：633 / 635

页数：3

共 18 条

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