2-CARBON AND 4-CARBON HOMOLOGATION OF ALDEHYDE BY AGCLO4-CATALYZED ADDITION OF ALKOXYALKENYLZIRCONOCENE CHLORIDE

被引：31

作者：

MAETA, H ^{[1
]}

SUZUKI, K ^{[1
]}

机构：

[1] KEIO UNIV,DEPT CHEM,KOHOKU KU,YOKOHAMA,KANAGAWA 223,JAPAN

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 02期

关键词：

D O I：

10.1016/S0040-4039(00)60583-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two- and four-carbon homologation of aldehyde is described, which is based on the AgClO4-catalyzed addition of zirconocene complexes, derived from hydrozirconation of 1-ethoxyethyne (1) and (Z)-1-methoxy-1-buten-3-yne (2) with Cp2Zr(H)Cl, followed by acidic hydrolysis.

引用

页码：341 / 344

页数：4

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