PERHYDROAZULENES .2. 2-TERT-BUTYLPERHYDROAZULEN-4-ONE SYSTEM

被引：22

作者：

HOUSE, HO

YAU, CC

VANDERVEER, D

机构：

[1] School of Chemistry, Georgia Institute of Technology, Atlanta

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 17期

关键词：

D O I：

10.1021/jo01331a015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

After conjugate addition of an allyl group to the enone 5, subsequent hydrobromination and base-induced cyclization formed the cis (1) and trans (2) isomers of the 2-tert-butylperhydroazulen-4-one system. Each of these ketones was converted to an appropriate solid derivative, and the structures and conformations of these solid derivatives were established by X-ray crystallography. © 1979, American Chemical Society. All rights reserved. © 1979, American Chemical Society. All rights reserved.

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页码：3031 / 3036

页数：6

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