DIRECT IDENTIFICATION OF REACTIVE ROUTES IN THE REACTION OF OXYGEN-ATOMS WITH DIMETHYLAMINE

被引：15

作者：

SLAGLE, IR

DUDICH, JF

GUTMAN, D

机构：

[1] Department of Chemistry, Illinois Institute of Technology, Chicago

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 61卷 / 03期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0009-2614(79)87187-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gaseous reaction of oxygen atoms with dimethylamine was studied in a cross-jet reactor and found to proceed by electrophilic addition to form an energy-rich N-oxide which rearranges to an hydroxylamine and then decomposes via three routes: (CH3)2 N + OH, CH3NCH2 + H2O and CH3NHO + CH3. © 1979.

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页码：620 / 624

页数：5

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