EFFECT OF SODA-ADDITIVE PULPING ON MOLECULAR CHARACTERISTICS OF RESIDUAL PULP LIGNIN

被引:10
作者
KOSIKOVA, B
MLYNAR, J
机构
[1] Slovak Academy of Sciences Institute of Chemistry
关键词
D O I
10.1080/02773819208545233
中图分类号
TB3 [工程材料学]; TS [轻工业、手工业、生活服务业];
学科分类号
0805 ; 080502 ; 0822 ;
摘要
The soda-additive pulps of pine wood were compared to corresponding soda and kraft pulps in respect to the macromolecular properties of the residual pulp lignins. Results of measurements of number and weight-average molecular weights as well as branching parameters show that the presence of additives such as anthraquinone, methanol and O2-pretreatment significantly causes the breaking of cross-links in the pulp lignin. On the other hand, ethylenediamine and hydrosulfide ion contribute mainly to extensive lignin degradation. The influence of used additives on the condensation reactions of the residual lignin has also been studied.
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页码:243 / 259
页数:17
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