OXIDATIVE CONVERSION OF CH4 ON NI AND AG ELECTRODE-CATALYSTS IN MOLTEN CARBONATE FUEL-CELL REACTOR

被引：5

作者：

BELYAEV, VD

SOBYANIN, VA

PARMON, VN

FRENI, S

AQUINO, M

机构：

[1] INST CATALYSIS,PROSP AKAD LAVRENTIEVA 5,NOVOSIBIRSK 630090,RUSSIA

[2] INST CNR TAE,I-98126 ST LUCIA,ITALY

来源：

CATALYSIS LETTERS | 1993年 / 17卷 / 3-4期

关键词：

OXIDATIVE COUPLING OF METHANE; MOLTEN CARBONATE FUEL CELL; SILVER AND NICKEL ELECTRODE-CATALYSTS;

D O I：

10.1007/BF00766144

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A fuel cell system using molten carbonates of potassium and lithium as electrolyte was applied to the oxidative conversion of methane over Ni and Ag electrodes. A possibility of cogeneration of valuable chemicals, like C2-hydrocarbons, and electricity in such a system was demonstrated. With CO32- ions (oxygen) transported electrochemically, the rate of formation of C2-hydrocarbons and selectivity for them on the Ag electrode were found to be greater than those with oxygen premixed to the gase phase.

引用

页码：213 / 221

页数：9

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