THE HYDROXYLATION OF GLOBULOL AND 7-EPIGLOBULOL BY CEPHALOSPORIUM-APHIDICOLA

被引：14

作者：

HANSON, JR

HITCHCOCK, PB

MANICKAVASAGAR, R

机构：

[1] School of Molecular Sciences, University of Sussex, Brighton

来源：

PHYTOCHEMISTRY | 1994年 / 37卷 / 04期

关键词：

CEPHALOSPORIUM APHIDICOLA; GLOBULOL; 7-EPIGLOBULOL; SESQUITERPENOID; MICROBIOLOGICAL HYDROXYLATION;

D O I：

10.1016/S0031-9422(00)89521-7

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Globulol and 7-epiglobulol were shown to be hydroxylated by Cephalosporium aphidicola on one (C-14) of the methyl groups geminal to the cyclopropane ring in 48.5 and 56% yield, respectively. The significance of this hydroxylation adjacent to a cyclopropane ring is noted.

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收藏

页码：1023 / 1025

页数：3

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