A NEW PYRAZOLYLBORATE ZINC HYDROXIDE COMPLEX CAPABLE OF CLEAVING ESTERS, AMIDES AND PHOSPHATES

被引：80

作者：

RUF, M ^{[1
]}

WEIS, K ^{[1
]}

VAHRENKAMP, H ^{[1
]}

机构：

[1] UNIV FREIBURG,INST ANORGAN & ANALYT CHEM,D-79104 FREIBURG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 02期

关键词：

D O I：

10.1039/c39940000135

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The L(2). Zn-OH complex of the new ligand L(2) = hydrotris(3-p-isopropylphenyl-5-methylpyrazolyl)borate is a strong nucleophile which effects cleavage of activated esters, amides, non-activated phosphorus acid esters and diphosphates, thereby providing stoichiometric models of esterase; peptidase and phosphatase enzyme activity.

引用

页码：135 / 136

页数：2

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