A LINEAR SWEEP VOLTAMMETRY THEORY FOR IRREVERSIBLE ELECTRODE-REACTIONS WITH AN ORDER OF ONE OR HIGHER .1. MATHEMATICAL FORMULATION

被引：13

作者：

KOHLER, H ^{[1
]}

PIRON, DL ^{[1
]}

BELANGER, G ^{[1
]}

机构：

[1] INST RECH ELECT QUEBEC,VARENNES J0L 2P0,QUEBEC,CANADA

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1987年 / 134卷 / 01期

关键词：

ELECTRIC MEASUREMENTS - Theory - Electrochemistry - ELECTRODES - Theory - WATER - Electrolysis;

D O I：

10.1149/1.2100388

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The development of new cheaper technological alternatives to water electrolysis for the production of hydrogen creates the need for a better understanding of irreversible electrode reactions with a reaction order higher than 1. This communication presents in the first part the mathematical derivation of a generalized theory of linear sweep voltammetry for irreversible electrode processes. It makes it possible to study the mechanisms and electrochemical reactions and to determine reaction orders of 1 and higher.

引用

页码：120 / 125

页数：6

共 19 条

[1] ELECTROCHEMICAL ASPECTS OF THE H2SO4-SO2 THERMOELECTROCHEMICAL CYCLE FOR HYDROGEN-PRODUCTION [J].