DIARYLDIACYLOXYSPIROSULFURANES .1. SYNTHESES FROM SULFIDES WITH HALOGENATING AGENTS

被引:31
作者
KAPOVITS, I
RABAI, J
RUFF, F
KUCSMAN, A
机构
[1] Institute of Organic Chemistry, L. Eötvös University, H-1445 Budapest
关键词
D O I
10.1016/0040-4020(79)80012-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A series of diaryldiacyloxyspirosulfuranes has been prepared from bis(2-carboxyaryl) sulfides with different halogenating agents. In pyridine, sulfides with two electron-withdrawing nitro groups cannot be converted into spirosulfuranes, suggesting the participation of pyridine in Cl+-transfer reactions. UV and IR spectroscopic data for spirosulfuranes are also reported and briefly discussed. © 1979.
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页码:1869 / 1874
页数:6
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