CHAIN CONFORMATIONS AND LOCATIONS OF PARTS OF A BLOCK POLYMER IN A LAMELLAR STRUCTURE

被引：29

作者：

MATSUSHITA, Y ^{[1
]}

MORI, K ^{[1
]}

SAGUCHI, R ^{[1
]}

NODA, I ^{[1
]}

NAGASAWA, M ^{[1
]}

CHANG, T ^{[1
]}

GLINKA, CJ ^{[1
]}

HAN, CC ^{[1
]}

机构：

[1] NATL INST STAND & TECHNOL,MAT SCI & ENGN LAB,GAITHERSBURG,MD 20899

来源：

MACROMOLECULES | 1990年 / 23卷 / 20期

关键词：

D O I：

10.1021/ma00222a010

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The chain conformation and location of parts of a block polymer in a lamellar structure of diblock copolymers of styrene and 2-vinylpyridine were studied by small-angle neutron scattering. It was found that the chain adjacent to the junction between the two blocks is located near the boundary between domains and is contracted along the direction parallel to the lamellae to the same extent as a whole block chain with the same molecular weight, while the chain at the free end of block polymer is located in the middle of domain and is unperturbed. © 1990, American Chemical Society. All rights reserved.

引用

页码：4387 / 4391

页数：5

共 18 条

[1] CONFORMATION OF POLYMER-CHAIN IN BULK
COTTON, JP
DECKER, D
BENOIT, H
FARNOUX, B
HIGGINS, J
JANNINK, G
OBER, R
PICOT, C
CLOIZEAU.JD
[J]. MACROMOLECULES, 1974, 7 (06) : 863 - 872
[2] NEW ITERATIVE METHOD FOR COLLIMATION CORRECTION IN SMALL-ANGLE SCATTERING
GLATTER, O
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1974, 7 (APR1) : 147 - 153
[3] THE SMALL-ANGLE NEUTRON-SCATTERING SPECTROMETER AT THE NATIONAL-BUREAU-OF-STANDARDS
GLINKA, CJ
ROWE, JM
LAROCK, JG
[J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 : 427 - 439
[4] SANS AND SAXS STUDIES ON MOLECULAR-CONFORMATION OF A BLOCK POLYMER IN MICRODOMAIN SPACE
HASEGAWA, H
HASHIMOTO, T
KAWAI, H
LODGE, TP
AMIS, EJ
GLINKA, CJ
HAN, CC
[J]. MACROMOLECULES, 1985, 18 (01) : 67 - 78
[5] BLOCK COPOLYMER THEORY .4. NARROW INTERPHASE APPROXIMATION
HELFAND, E
WASSERMAN, ZR
[J]. MACROMOLECULES, 1976, 9 (06) : 879 - 888
[6] HELFAND E, 1975, MACROMOLECULES, V8, P522
[7] EQUILIBRIUM MORPHOLOGY OF BLOCK COPOLYMER MELTS .2.
KAWASAKI, K
OHTA, T
KOHROGUI, M
[J]. MACROMOLECULES, 1988, 21 (10) : 2972 - 2980
[8] KAWASAKI K, UNPUB MACROMOLECULES
[9] PHASE-CONTRAST MATCHING IN LAMELLAR STRUCTURES COMPOSED OF MIXTURES OF LABELED AND UNLABELED BLOCK COPOLYMER FOR SMALL-ANGLE NEUTRON-SCATTERING
MATSUSHITA, Y
NAKAO, Y
SAGUCHI, R
MORI, K
CHOSHI, H
MUROGA, Y
NODA, I
NAGASAWA, M
CHANG, TH
GLINKA, CJ
HAN, CC
[J]. MACROMOLECULES, 1988, 21 (06) : 1802 - 1806
[10] STUDIES OF STYRENE AND 2-VINYLPYRIDINE BLOCK COPOLYMERS - PREPARATION AND CHARACTERIZATION
MATSUSHITA, Y
NAKAO, Y
SAGUCHI, R
CHOSHI, H
NAGASAWA, M
[J]. POLYMER JOURNAL, 1986, 18 (06) : 493 - 499

← 1 2 →